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Metallurgy · Understanding manipulation

Copper–nickel alloy formation

Link composition, fusion and solidification of an alloy.

Reading · approximately 4 min2 relationships explainedquiz · 3 questions
01 · The scientific principle

What is happening?

An alloy combines several elements in a metallic material. The Cu–Ni system is a classic example of extended solid solubility; its solidification is described with liquid, solid and two-phase domains.

In a domain with two phases at equilibrium, the composition of each phase generally differs from the average composition. The lever rule relates these compositions to the fractions of the phases.

02 · Relationships to know

The formulas, with their conditions.

C₀ = Σ(mᵢ Cᵢ)/Σmᵢ

C₀: average composition; mᵢ: masses; Cᵢ: compositions on the same basis.

Use when: Mixture balance before losses or reactions.

fα = (Cβ − C₀)/(Cβ − Cα)

fα: phase fraction α; Cα, Cβ: compositions at the ends of the bond line.

Use when: Two-phase equilibrium, C₀ between Cα and Cβ and basis of coherent composition.

03 · From laboratory to industry

Where is this principle used?

Alloy foundry

Develop a composition and monitor its solidification.

Manufacturing of Cu–Ni components

Choose the properties of a material according to its application.

What to observe in the experiment

Mix two charges of known compositions, calculate C₀ then follow the two-phase zone during cooling.

To learn more

References and readings

This sheet explains the principles and their assumptions. Educational simulation can simplify the process; an industrial model requires suitable data and validation.

04 · Your turn

Have you understood the essentials?

Only one correct answer per question. Answer all three questions, then view the answer key.

1. The average composition of a mixture depends…
2. In a liquid + solid zone, do the two phases always have the same composition?
3. The lever rule determines in particular…
Intu Lab · Understanding sheet · Kimba Christian